Rapid Solid-State Photopolymerization of Cyclic Acetal-Containing Acrylates
نویسندگان
چکیده
منابع مشابه
Enantioselective hydrogenation of tetrasubstituted olefins of cyclic beta-(acylamino)acrylates.
Hydrogenation of a series of cyclic beta-(acylamino)acrylates with tetrasubstituted olefins has been accomplished successfully with the use of Ru catalysts with chiral biaryl ligands such as C3-TunaPhos, and up to over 99% ee's have been achieved. This methodology provides an efficient catalytic method for the synthesis of both cis and trans chiral cyclic beta-amino acid derivatives.
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ACRYLATES HAVE been around since the 1930s, when Rohm and Haas began mass production of Plexiglas, a clear and resistant glass substitute made of polymerized methacrylate. It is used extensively for windowpanes, airplane canopies, car lights and windshields, streetlamps, and so on. Numerous other acrylates have been synthesized and have found applications in paints and adhesives, dental composi...
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ژورنال
عنوان ژورنال: Macromolecules
سال: 2009
ISSN: 0024-9297,1520-5835
DOI: 10.1021/ma802406j